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To start with, the $test_var variable contains 8.23, a floating-point value. Next, $test_var is converted to a string, which means that the number 8.23 is now stored using the characters 8, . (period), 2, and 3. After converting $test_var to an integer type, it contains the value 8; in other words, the fractional part of the number has been lost permanently. You can see this in the next two lines, which convert $test_var back to a float and display its contents. Even though $test_var is a floating-point variable again, it now contains the whole number 8. Finally, after converting $test_var to a Boolean, it contains the value true (which PHP displays as 1). This is because PHP converts a non-zero number to the Boolean value true. Find out more about what PHP considers to be true and false in the Logical Operators section later in this chapter.

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Convert Image to PDF in C#, VB.NET. Step1: Use C#/VB.NET to create a PDF document. In this step, you need to create a new PDF file first, then, add a section in the newly built PDF, at last, add a page in the section that you just added. Step2: Load an image to PDF and set image location. Step3: Save the image to PDF ...

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FeedDemon (version 1.5), at http://bradsoft.com/, sells for $29.95. This is one of the most popular commercial news aggregators on the market and is a feature-rich application. FeedDemon was one of the first commercial news aggregators to implement podcast-download support. FeedDemon supports automatic updates to your media player and works with both Windows Media Player and Apple iTunes. You may visit sites and read the news, but if you don t want to listen to their podcasts, you can specify on a site-by-site basis whether you want the application to automatically download podcasts. This aggregator has a separate download client, appropriately called FeedStation. Within FeedStation, you can configure where your files will be stored and which media player to use. Those of you already using FeedDemon have all the tools you need to start downloading podcasts immediately (see Figure 2-12).

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Clearly, the error ec (x), which is the error of the central difference approximation (1) f c (x) to f (1) (x), is proportional to h2 . Thus, if f (x) is smooth enough, the central difference approximation is more accurate than the forward or backward difference approximations. The errors ef (x), eb (x), and ec (x) are truncation errors in the approximations. Of course, when implementing any of these approximations on a computer there will be rounding errors, too. Each approximation can be expressed in the form 1 f (1) (x) = f T y, h where for the forward difference approximation f = [f (x) f (x + h)]T , y = [ 1 1]T , for the backward difference approximation f = [f (x h) f (x)]T , y = [ 1 1]T , (9.140b) (9.140a) (9.139)

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symmetric (S) or both antisymmetric (A) with respect to a preserved symmetry operation If fa and fb have di erent symmetry properties, one S and the other A, then the spatial symmetry of the diradical states is A Notice that the latter case could not arise if fa and fb are the orbitals involved in the original bond, since they could not have interacted to form the bond if they were of di erent symmetry It will generally happen that one or more of the orbitals of the fragments a and b will be comparable in energy to fa and fb so that other diradical and zwitterionic states must be considered and the situation of di erent symmetries may occur among these The same holds true for the reactant excited states.

As mentioned earlier, heterolytic cleavage of a bond to form charged species is never observed in the gas phase and is very unlikely in nonpolar solvent Thus the expected overall order of the energies of the product states arising from the bond rupture is E 3 D E 1 D ` E Z1 ` E Z2 If the energy separation of fa and fb is large, or if fa and/or fb are di use, that is, the Coulomb repulsion of two electrons in the same MO (neglected in Huckel theory) is not large, the energy separation of the diradical states from Z1 may not be very large and may indeed be reversed if the dissociation is carried out in a highly polar solvent like water Examination of several reactions of carbonyl compounds will serve to exemplify the principles of Dauben Salem Turro analysis.

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NORRISH TYPE II REACTION OF CARBONYL COMPOUNDS A common photochemical reaction of carbonyl compounds is the transfer of a hydrogen atom to the carbonyl oxygen atom:.

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